Article:
Water
Quality Problems: Health and Household
Dale Dorman, MS
Extension Housing & Environment Specialist
Department of Housing and Consumer Economics
When
you fill a glass with water from your tap, you expect to
drink water that is pure and safe. But how safe is it?
Water contains impurities
from natural and man-made sources, such as minerals, gases,
bacteria, metals and chemicals. Many of these impurities
are harmless. However, some impurities can adversely affect
your health. Others can damage equipment, stain laundry
and fixtures and emit odors.
To protect the public health
and ensure uniform standards for water quality nationwide,
Congress passed the Safe Drinking Water Act of 1974. This
act and its amendments authorized the U.S. Environmental
Protection Agency (EPA) to establish limits on the concentration
of certain contaminants in public water supplies (systems
serving more than 25 people or 15 year-round connections).
Private water supplies, including wells, are not regulated
by drinking water standards. The owner must test and treat
the water as needed to avoid health risks.
Drinking Water Standards
The
EPA standards for drinking water fall into two categories
– Primary Standards and Secondary Standards.
Primary Drinking Water
Standards regulate contaminants that affect the safety of drinking water and
may cause health problems. These standards are enforced
by EPA. They protect you from three classes of toxic pollutants:
microbial pathogens, radioactive elements and organic/inorganic
chemicals. Many of these contaminants occur naturally in
trace amounts in ground or surface water. Primary Standards
set a limit, called the Maximum Contaminant Level (MCL)
on the highest amount of a specific contaminant allowed
in the drinking water supplied by a public water system.
The MCL is usually expressed in milligrams per liter (mg/L).
See Chart I for Primary Drinking water standards including
organic/inorganic chemicals, radioactive elements and microbial
pathogens.
Secondary Drinking Water
Standards regulate contaminants that affect the aesthetic qualities of drinking
water such as taste, odor, color and appearance. The concentration
limit is called the Secondary Maximum Contaminant Level
(SMCL). SMCLs are established for chloride, color, copper,
corrosivity, foaming agents, iron, manganese, odor, pH,
sulfates, total dissolved solids and zinc. Secondary Standards
are not enforced; water systems are not required to test
for and remove secondary contaminants. Secondary levels
represent reasonable goals and serve as useful guidelines
for water suppliers who wish to ensure that their water
is suitable for all household uses. See Chart II for Secondary
Drinking water standards including inorganic chemicals and
physical problems.
Setting Standards
EPA
regulations develop Primary Standards for drinking water
based on three criteria:
- The contaminant causes adverse health effects.
- It is detectable in drinking water.
- It is known to occur in drinking water.
In
setting Primary Standards for a drinking water contaminant,
research scientists first look at all the toxicological
data on that water contaminant. This data is usually the
result of studies that have been conducted on animals. Occasionally
human clinical or epidemiological data are also available.
Scientists use this information to estimate the concentration
of a drinking water contaminant that may be toxic and the
concentrations, if any, that may cause no adverse effects.
The levels of contaminants
found in drinking water are seldom high enough to cause
acute health effects –
effects that occur almost immediately after exposure to
a large dose of a substance. Therefore, scientists are most
concerned about chronic health effects such as
cancer, birth defects, miscarriages, nervous system disorders
and organ damage. These health effects may occur after prolonged
exposure to small amounts of a substance. When scientists
set drinking water standards, they treat contaminants that
cause cancer (carcinogens) differently from contaminants
that cause other health effects.
Non-Cancer Causing Contaminants
For
non-cancer causing toxic substances, scientists set standards
using a figure calculated from animal studies called the
reference dose. The reference dose is
the amount of a substance that a person can consume daily,
over a lifetime, without suffering any adverse health effects.
It includes a conservative margin. The reference dose used
to be called acceptable daily intake.
EPA regulators use the
reference dose to establish a Maximum Contaminant Level
Goal (MCLG) for a water contaminant. The MCLG is the concentration
of a contaminant that experts believe a person can consume
safely over a lifetime. It is based entirely on health considerations
and is set at a level where no adverse health effects should
occur. The MCLG is not enforced by the EPA. It is the goal
used to set enforceable drinking water standards.
The Maximum Contaminant
Level (MCL) is the enforceable Primary Drinking water Standard.
It is set as close as possible to the MCLG. In setting an
MCL, EPA regulators consider, in addition to health effects,
the feasibility and the combined cost of analyzing water
for a contaminant and for treating water to remove the contaminant.
Therefore, the MCL is often less stringent than the MCLG.
Cancer
Causing Contaminants
In
setting Primary Standards for substances believed to cause
cancer, research scientists assume that no concentration
is safe. Consequently, the MCLG is set at zero. But a zero
level is not always possible to achieve, so regulators estimate
toxicity by calculating a figure called a risk estimate.
In theory, any concentration
of a carcinogen in your drinking water may possibly cause
cancer. In practice, however, at very low concentrations
the risk of cancer becomes so small that it is considered
negligible. Therefore, scientists must decide what level
of risk is acceptable. It may be one excess cancer in 10,000
persons or one excess cancer in 1 million persons exposed
over a lifetime (70 years). The concentration of the substance
estimated to cause this acceptable level of risks is the
risk estimate. Based on the risk estimate, EPA regulators establish
the MCLs for cancer-causing contaminants.
Setting drinking water
standards is an imperfect process. Data relating human health
effects to contaminants in drinking water are limited, and
scientists have difficulty predicting the effects of drinking
small amounts of a substance for many years. In addition,
regulatory decisions frequently incorporate economic, political
and social considerations.
Although current drinking
water standards do not guarantee that the glass of water
you draw from your tap will be absolutely safe and pure,
they do reflect sound scientific judgment. Standards are
based on all available knowledge.
Federal, State and Local Responsibilities
Under
the Safe Drinking Water Act, the primary role of the federal
government is to develop national drinking water regulations
that will protect public health and welfare. The states
have the responsibility for monitoring public water systems
and enforcing drinking water standards for EPA - regulated
contaminants and other contaminants. The local public water
systems are responsible for treating and testing drinking
water to ensure that water quality consistently meets the
standards set by the regulation.
When levels go above a
standard, the EPA requires that the water contaminant levels
be reduced to the Maximum Contaminant Level. The corrective
treatment is left to the public water system. In addition,
Federal law requires that the water system must notify the
public when a drinking water standard has been violated.
Public notification must include clear explanations of the
violations; information on potential adverse health effects;
the steps being taken to correct the problem; and the need,
if any, to seek alternative water supplies. This procedure
is a safety precaution intended to keep the public informed
and call attention to deficiencies in the drinking water
supply.
Consumer Rights
Under
the Safe Drinking Water Act Amendment of 1986, consumers
have the right to obtain the following information about
their drinking water:
- its source,
- where it is purified,
- the contaminants for which it has been tested,
- past and present contamination problems,
- contamination levels that violate current federal
drinking water standards, and
- how the public was notified about the violations.
Protection
under the Safe drinking water Act of 1974 includes:
- the right to bring civil suits against the local
water system, the state, or federal officials if they
fail to do their jobs;
- the requirement of public water systems to chemically
treat contaminated water or install clean-up equipment
to remove the contaminant(s) to concentrations below the
standard when a violation occurs;
- the requirement for public notification of maximum
contaminant level violations within 14 days of their detection
and at least once every three months if the contamination
continues. For minor violations of standards, public notification
must be made once a year.
Chart I
Primary Drinking
Water Standards – Regulated
Organics
| Contaminant |
Source |
Possible chronic health effects |
MCL |
| Acrylamide* |
drinking water treatment residue; well drilling; food production
and processing; paper making and textile manufacturing.
|
cancer and nervous system effects. |
MCL: 0.05% dosed at 1 mg/L |
| Alachlor* (Lasso) |
agricultural herbicide |
cancer; damage to eyes and liver |
MCL: 0.002 mg/L |
| Aldicarb* (Temik) |
agricultural insecticide |
cholinesterase inhibition. |
MCL: 0.003 mg/L |
| Aldicarb sulfoxide* |
agricultural insecticide |
cholinesterase inhibition. |
MCL: 0.004 mg/L |
| Aldicarb sulfone* |
agricultural insecticide |
cholinesterase inhibition. |
MCL: 0.002 mg/L |
| Benzene |
leaking underground fuel storage tanks; industrial wastes; manufacture
of pesticides, detergents and solvents. |
leukemia and other cancers; nerve, lung, and kidney damage; blood
disorders and reproductive effects. |
MCL: 0.005 mg/L |
| Carbofuran*
(Furadan 4F) |
agricultural insecticide |
cholinesterase inhibition; reproductive and immune system effects.
|
MCL: 0.04 mg/L |
| Carbon Tetrachloride |
chemical disposal sites, contaminated soils, and landfills; aerosol
sprays, cleaning agents and coolants; laundry and
dry-cleaning operations. |
cancer; central nervous system depression; liver and kidney damage.
|
MCL: 0.005 mg/L |
| Chlordane* |
insecticide; hazardous waste sites |
cancer; nerve and liver effects. |
MCL: 0.002 mg/L |
| 2,4-D* (Formula 40, Weedar 64) |
agricultural herbicide and aquatic weeds control. |
liver and kidney damage; skin irritations and muscle effects. |
MCL: 0.07 mg/L |
| Dibromochloropropane* (DBCP, Wemafume) |
soil fumigant. |
cancer, kidney and liver damage; infertility. |
MCL:0.0002 mg/L |
| p-Dichlorobenzene |
dye and pesticide manufacturing. |
liver and kidney damage; blood disorders. |
MCL: 0.075 mg/L |
| 1,2-Dichloroethane |
vinyl manufacturing; drycleaning solvent, metal degreasers, and
adhesives; gasoline additive. |
cancer; central nervous system depression; kidney and liver damage;
lung and heart damage. |
MCL: 0.005 mg/L |
| 1,1-Dichloroethylene |
industrial solvent, cleaning and degreasing agent. |
central nervous system depression; liver, kidney and heart damage.
|
MCL: 0.007 mg/L |
| trans-1,2-Dichloroethylene* |
transformed from other chlorinated hydrocarbons in drinking water
supplies; industrial cleaning and degreasing agents.
|
liver and kidney damage. |
MCL: 0.1 mg/L |
| cis-1,2-Dichloroethylene* |
transformed from other chlorinated hydrocarbons in drinking water
supplies; industrial cleaning and degreasing agents.
|
liver and kidney damage. |
MCL: 0.07 mg/L |
| 1,2-Dichloropropane* |
industrial solvent and cleaning agents; dry cleaning fluid components,
soil fumigants. |
liver and kidney damage. |
MCL: 0.005mg/L |
| Endrin |
insecticide and rodenticide. |
liver and nervous system effects; birth defects. |
MCL: 0.0002mg/L |
| Epichlorohydrin* |
resin and rubber product manufacturing; contamination of materials
used to process food and treat or store drinking water.
|
cancer; central nervous system, lung, liver and kidney effects;
damage to male reproductive organ. |
MCL: 0.01% dosed at 20 mg/L |
| Ethyl benzene* |
hazardous waste sites and styrene production. |
nerve, brain, liver and kidney effects. |
MCL: 0.7 mg/L |
| Ethylene dibromide* |
pesticide and soil fumigants; leaded gasoline additives. |
nerve, brain, kidney, nervous system, gastrointestinal, and reproductive
effects. |
MCL: 0.00005 mg/L |
| Heptachlor expoxide* |
insecticide and hazardous waste sites. |
cancer, liver damage and central nervous system effects. |
MCL: 0.0002 mg/L |
| Heptachlor* (H-34, Heptox) |
insecticide and hazardous waste sites. |
cancer, liver damage and central nervous system effects. |
MCL: 0.0004 mg/L |
| Lindane* |
pesticides. |
liver and kidney damage. |
MCL: 0.002 mg/L |
| Methoxychlor* |
insecticides. |
nervous system, kidney, and liver effects. |
MCL: 0.04 mg/L |
| Pentachlorophenol*
(PCP) |
herbicides and insecticides; water contact with PCP-treated wood;
industrial waste sites. |
liver and kidney damage; nervous system, immune system, and reproductive
effects; blood disorders. |
MCL: 0.001 mg/L |
| Polychlorinated biphenyls* (PCBs, Aroclor) |
hazardous waste sites; disposal and manufacture of electrical transformers,
electromagnets, fluorescent lights and plastic |
cancer; liver damage. |
MCL: 0.0005 mg/L |
| Styrene* |
manufacture of plastics, synthetic rubbers, resins and insulators.
|
liver damage. |
MCL: 0.1 mg/L |
| Tetrachloroethylene* |
industrial metal, textile and dry-cleaning solvent. |
cancer; liver and kidney damage; central nervous system depression.
|
MCL: 0.005 mg/L |
| Toluene* |
paint, oil, resin manufacturing; leaking fuel storage tanks; jet
fuel. |
central nervous system depression; kidney damage. |
MCL: 1 mg/L |
| Toxaphene* |
insecticides. |
cancer, liver and kidney damage. |
MCL: 0.003 mg/L |
| 2,4,5-TP* (Silvex) |
herbicides. |
liver and kidney damage. |
MCL: 0.05 mg/L |
| 1,1,1-Trichloroethane |
hazardous waste sites; industrial solvent and degreasers; drycleaning
solvents. |
central nervous system depression; liver and cardiovascular damage.
|
MCL: 0.20 mg/L |
| Trichloroethylene (TCE) |
hazardous waste sites, drycleaning solvent; manufacturing of chemicals
and drugs. |
cancer, nervous system depression and heart effects; liver and
kidney damage. |
MCL: 0.005 mg/L |
| Total Trihalomethanes |
formed when residual chlorine in treated drinking water combines
with naturally occurring organic matter. |
cancer; heart, lung, kidney and liver damage. |
MCL: 0.100 mg/L
MCLG: - |
| Vinyl Chloride |
manufacturing of plastics and synthetic rubber; corrosion of plastic
pipes and soldering. |
cancer; central nervous system depression; liver, reproductive,
and digestive tract effects; birth defects. |
MCL: 0.002 mg/L |
| Xylene* |
leaking underground fuel storage tanks; manufacturing of chemicals
and drugs. |
nervous system and reproductive effects. |
MCL: 10 mg/L |
The
units of measurement are milligrams per liter (mg/L), micrometers
(um) and picoCuries (pCi).
*New
standard - Effective 1992 with monitoring requirements to
begin January 1, 1993.
Inorganics
| Contaminant |
Source |
Possible chronic health effects |
MCL |
| Arsenic |
rocks and soil; may contaminate commercial phosphates in fertilizers
and laundry detergents; pesticide residues; smelting,
glass making and coal mining. |
skin and lung cancer; liver and kidney damage. |
MCL: 0.05 mg/L |
| Asbestos* |
corrosion of asbestos-cement pipe in water distribution systems;
manufacture of cement products, paper, floor tiles,
paint, caulking, textiles and plastics. |
lung cancer; gastrointestinal cancer when swallowed fibers exceed
10um. |
MCL: -7 million fibers (>10um long)/liter (MFL) |
| Barium* |
rocks and soil; coal and gas mining; coal burning; diesel fuel
combustion and jet fuel; paints, bricks and tiles.
|
hypertension and heart damage. |
MCL: 2.0 mg/L |
| Cadmium* |
rocks, coal, and petroleum; by-product of mining, smelting, refining
and electroplating; discarded batteries, paints, and
plastics; corrosion of galvanized pipe; landfills
and industrial waste sites; fertilizers and sewage
sludge. |
kidney damage. |
MCL: 0.005 mg/L |
| Chromium* |
rocks and soil; mining sites; chrome plating, cement production;
waste incineration; contaminated laundry detergent
and bleaches; septic systems. |
liver, kidney and lung damage. |
MCL: 0.1 mg/L |
| Copper* |
rocks and soil; coal burning; iron and steel production; industrial
and sewage treatment plant wastes; corrosion of brass
and copper pipes. |
anemia; digestive disturbances; liver and kidney damage. |
MCL: 1.3 mg/L (action level) |
| Fluoride |
rocks and soil; industrial wastes. |
mottling of teeth; bone damage. |
MCL: 4.0 mg/L |
| Lead* |
rocks and soil; corrosion of lead pipes and lead-soldered pipe
joints; combustion of leaded gasoline; smelter emissions
and discarded storage batteries. |
brain and nerve damage, especially in children; kidney damage;
digestive disturbances; blood disorders; hypertension.
|
MCL: 0.015 mg/L (action level)
|
| Mercury |
soil and rocks; mining, smelting, coal burning; electrical equipment
and fungicides |
brain and nerve damage; kidney damage; birth defects and skin rash.
|
MCL: 0.002 mc/L |
| Nitrate |
soils and mineral deposits; fertilizers, sewage and animal wastes.
|
Methemoglobinemia in infants. |
MCL: 10 mg/L nitrate-nitrogen, 45 mg/L nitrate |
| Selenium* |
soil and shales; coal burning, mining, smelting; manufacture of
glass, paints and drugs; fungicides and feed additives.
|
growth inhibition; skin discoloration; dental and digestive problems;
liver damage and psychological disorders. |
MCL: 0.05 mg/L |
| Silver |
soil, coal and mineral deposits; ore mining and manufacture of
alloys; photographic procedures and jewelry making.
|
agyria, a permanent blue-gray discoloration of skin, mucous membranes
and eyes. |
MCL: 0.05 mg/L |
The
units of measurement are milligrams per liter (mg/L), micrometers
(um) and picoCuries (pCi).
*New
Standard - Effective 1992 with monitoring requirements to
begin January 1, 1993.
Microbial Pathogens
| Contaminant |
Source |
Possible chronic health effects |
MCL |
| Coliform Bacteria (an indicator organism for fecal coliform, streptococcal,
and other pathogenic bacteria). |
sewage, animal wastes; backflow or improper pipe connections in
water systems; improperly sealed or constructed wells.
|
gastroenteritis, salmonella infection, dysentery, typhoid fever
and cholera. |
MCL: <1/100 ml |
| Giardia lamblia |
sewage and animal wastes. |
giardiasis (a gastrointestinal infection causing diarrhea, abdominal
cramps and gas). |
MCL: Treatment 99.9% effective
|
| Viruses |
sewage |
gastroenteric and other viral diseases; hepatitis. |
MCL Treatment 99.9% effective. |
The
units of measurement are milligrams per liter (mg/L), micrometers
(um) and picoCuries (pCi).
*New
Standard - Effective 1992 with monitoring requirements to
begin January 1, 1993.
Radioactive Elements
| Contaminant |
Source |
Possible chronic health effects |
MCL |
| Gross Alpha Particles |
natural decay or uranium in rocks and soil. |
cancer; bone and kidney damage. |
MCL: 15 pCi/L |
| Radium-226,-228 |
natural decay of uranium in rocks and soil. |
bone cancer; bone and kidney damage; birth defects. |
MCL: 5 pCi/L |
| Radon |
decay of uranium in soils and rocks. |
lung cancer, when released as a gas and inhaled. |
MCL: pending |
| Uranium |
soil and rocks |
cancer and kidney damage. |
MCL: pending |
The
units of measurement are milligrams per liter (mg/L), micrometers
(um) and picoCuries (pCi).
Chart II
Secondary
Drinking Water Standards – Unregulated
Inorganic Contaminants
| Contaminant |
Source |
Symptoms |
SMCL* |
| Chloride |
natural minerals; seawater; road salt; fertilizers; industrial
wastes and sewage. |
salty taste; corroded pipes, fixtures and appliances; blackening
and pitting of stainless steel. |
250 mg/L |
| Copper |
leaching from copper water pipes and tubing; industrial and mining
wastes. |
bitter or metallic taste; blue-green stains on plumbing fixtures.
|
1.3 mg/L |
| Fluoride |
natural minerals and industrial wastes. |
brownish discoloration of teeth. |
2 mg/L |
| Iron |
natural deposits in rocks and soil; leaching of cast iron pipes
in water distribution systems. |
brackish color; rusty sediment; bitter metallic taste; brown-orange
stains; iron bacteria and discolored beverages. |
0.3 mg/L |
| Manganese |
natural deposits in rocks and soil. |
brownish color, black stains on laundry and fixtures; bitter taste;
altered taste of water-mixed beverages. |
0.05 mg/L |
| Sulfate |
natural deposits or salts; by-products of coal mining; industrial
wastes and sewage. |
bitter, medicinal taste; scaly deposits; corrosion; laxative effects;
"rotten-egg" odor from hydrogen sulfide
gas formation. |
250 mg/L |
| Total Dissolved Solids
(TDS) |
dissolved minerals; iron and manganese. |
hardness, scaly deposits; sediment; cloudy, colored water; odor;
staining; salty or bitter taste. |
500 mg/L |
| Zinc |
natural deposits; leaching of galvanized pipes and fittings. |
metallic taste. |
5 mg/L |
The
units of measurement are milligrams per liter (mg/L), micrometers
(um) and picoCuries (pCi).
Physical Problems
| Contaminant |
Source |
Symptoms |
SMCL |
| Color |
iron, copper, or manganese; organic chemicals; organic matter |
visible tint. |
15 color units |
| Corrosivity |
depends on temperature, acidity, hardness, and oxygen content of
water. |
pitted or leaking pipes; metallic taste; staining due to lead,
copper, iron or zinc dissolved from plumbing. |
noncorrosive |
| Detergents/
Foaming Agents |
household and industrial wastes. |
frothy, cloudy appearance; soapy taste and unpleasant odor. |
0.5 mg/L |
| Odor |
dissolved gases, minerals, chemicals; leaking underground storage
tanks; landfill or septic run-off; organic matter.
|
"rotten-egg," septic, musty or chemical smell. |
3 Threshold Odor Number (TON)
|
| pH |
dissolved acid and alkaline materials. |
pitting of pipes and fixtures, bitter or metallic taste (low pH);
slippery feel, soda taste, scaly deposits (high pH).
|
6.5 to 8.5 on pH scale. |
Water Hardness
Water
hardness does not have a Secondary Maximum Contaminant Level.
It is included here, however, because it is a common water
quality problem and testing for water hardness is frequently
necessary to evaluate and treat other problems. The source
is naturally dissolved calcium and magnesium from soil and
limestone. The symptoms are soap deposits; scaly deposits
in plumbing and appliances; and decreased cleaning action
of soaps and detergents. The degree of water hardness is
classified as follows:
| Water Hardness |
Grains per Gallon |
Parts per Million (ppm) |
| Soft |
0 to 3 |
0 to 60 |
| Moderate |
3 to 7 |
60 to 120 |
| Hard |
7 to 10 |
120 to 180 |
| Very Hard |
more than 10 |
more than 180 |
The
units of measurement are milligrams per liter (mg/L, micrometers
(um) and picoCuries (pCi